The Journal of chemical physics

T1 barrier height, S1–T1 intersystem crossing rate, and S0 radical dissociation threshold for H2CO, D2CO, and HDCO

MC Chuang, MF Foltz, CB Moore

Index: Chuang, Mei-Chen; Foltz, Mary F.; Moore, C. Bradley Journal of Chemical Physics, 1987 , vol. 87, # 7 p. 3855 - 3864

Full Text: HTML

Citation Number: 128

Abstract

Vacuum UV laser??induced fluorescence has been used to detect the atomic products in the photofragmentation of H2CO, D2CO, and HDCO. The dissociation is shown to occur on both the ground (S 0) and the first triplet (T 1) potential surfaces. The T 1 exit barrier height (2.9 ...

Related Articles:

Experimental and theoretical study of the F, Cl and Br reactions with formaldehyde and acetaldehyde

[Nielsen; Beukes; D'Anna; Bakken Physical Chemistry Chemical Physics, 2000 , vol. 2, # 18 p. 4049 - 4060]

Laser-induced fluorescence from the predissociating formyl radical. Part 2.—Analysis of dispersed emission from the ÖX transition

[Rumbles, Garry; Lee, Edward K. C.; Valentini, James J. Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 23 p. 3837 - 3841]

Tunneling in thermal unimolecular reactions: formaldehyde-d2

[Forst, Wendel Journal of Physical Chemistry, 1983 , vol. 87, # 25 p. 5234 - 5236]

Photo-tautomerization of acetaldehyde to vinyl alcohol: a potential route to tropospheric acids

[Andrews, Duncan U.; Heazlewood, Brianna R.; Maccarone, Alan T.; Conroy, Trent; Payne, Richard J.; Jordan, Meredith J. T.; Kable, Scott H. Science, 2012 , vol. 337, # 6099 p. 1203 - 1206]

More Articles...