Palladium-Catalyzed Arylation of tert-Cyclobutanols with Aryl Bromide via CC Bond Cleavage: New Approach for the γ-Arylated Ketones

T Nishimura, S Uemura

Index: Nishimura, Takahiro; Uemura, Sakae Journal of the American Chemical Society, 1999 , vol. 121, # 47 p. 11010 - 11011

Full Text: HTML

Citation Number: 112

Abstract

Palladium-catalyzed arylation of a wide variety of compounds with aryl halide has been developed in recent years as a powerful method to create an aromatic carbon-carbon bond1 as well as an aromatic carbon-heteroatom bond. 2 Recently, we have reported the palladium (II)-catalyzed oxidative ring cleavage of tert-cyclobutanols using oxygen as a reoxidant (Scheme 1), 3 in which we postulated that the CC bond of tert-cyclobutanols ...

Related Articles:

Generation of organotantalum reagents and conjugate addition to enones

[Shibata, Ikuya; Kano, Takeyoshi; Kanazawa, Nobuaki; Fukuoka, Shoji; Baba, Akio Angewandte Chemie - International Edition, 2002 , vol. 41, # 8 p. 1389 - 1392]

Ligand-Accelerated Pd-Catalyzed Ketone γ-Arylation via C–C Cleavage with Aryl Chlorides

[Ziadi, Asraa; Martin, Ruben Organic Letters, 2012 , vol. 14, # 5 p. 1266 - 1269]

Conjugate addition of benzyl copper reagents to α, α-enoates and-enones.

[Heerden, Pieter S. van; Bezuidenhoudt, Barend C. B.; Steenkamp, Jacobus A.; Ferreira, Daneel Tetrahedron Letters, 1992 , vol. 33, # 17 p. 2383 - 2386]

Free radical-promoted conjugate addition of activated bromo compounds using titanocene (III) chloride as the radical initiator

[Mandal, Samir Kumar; Jana, Samaraesh; Roy, Subhas Chandra Tetrahedron Letters, 2005 , vol. 46, # 36 p. 6115 - 6117]

Type II photoprocesses of phenyl ketones. Evidence for a biradical intermediate

[Wagner,P.J. et al. Journal of the American Chemical Society, 1972 , vol. 94, p. 7480 - 7488]

More Articles...