Helvetica Chimica Acta

Studies on Alkyl Nitrogen Bond Formation via Reductive Elimination from Monomeric Palladium Complexes in High Oxidation State

Á Iglesias, K Muñiz

Index: Iglesias, Alvaro; Muniz, Kilian Helvetica Chimica Acta, 2012 , vol. 95, # 10 p. 2007 - 2025

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Citation Number: 13

Abstract

Abstract Oxidation of a series of defined palladium (II) complexes bearing a bidentate ligand, and a methyl and an amidato substituent was carried out with the aim to gain a better understanding of the inherent requirements for C [BOND] N bond-formation from Pd complexes in high oxidation state. This work clarified the role of the individual nitrogen sources and has important implication for alkyl [BOND] nitrogen bond-forming reactions ...