One-step synthesis of esters of aliphatic. beta.-chloro sulfonic acids. Their sequential conversion to other sulfonic acid derivatives

MS Heller, DP Lorah, CP Cox

Index: Heller, Morgan S.; Lorah, Dennis P.; Cox, Charles G. Journal of Chemical & Engineering Data, 1983 , vol. 28, # 1 p. 134 - 137

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Citation Number: 2

Abstract

A one-step synthesis of methyl 2thiorohexane-1-and 2-chlorooctane-1-sulfonate by the novel free-radical addition of methyl chlorosulfonate to 1-hexene and 1-octene, respectively, Is reported. These products were converted by standard techniques into the corresponding sodium and benzylthiuronlum P-chiorosulfonlc acid salts and sulfonyl chlorides. Dehydrochlorination of these latter products with triethylamine afforded reglospecific ...