PIPERIDINE DERIVATIVES. V. THE PREPARATION AND REDUCTION OF CERTAIN PHENYL SUBSTITUTED 3-CARBETHOXY-4-PIPERIDONES. 1-CYCLOHEXYL- …

JR Thayer, SM McElvain

Index: Thayer; McElvain Journal of the American Chemical Society, 1927 , vol. 49, p. 2865

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Citation Number: 8

Abstract

In the reduction of the l-benzylpiperidone, there was no rapid initial absorption of hydrogen and both the ring and the ketone group seemed to reduce simultaneously. The reduction to a negative ferric chloride test took place in about 24 hours and required 65-75y0 of the theoretical amount of hydrogen necessary for the complete reduction of both the ring and ketone group. From this point the reduction was very slow but could be continued to a ...

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