The Journal of Organic Chemistry

Addition of silicon hydrides to olefinic double bonds. XII. Use of aminosilicon hydrides and silazane hydrides

WE Dennis, JL Speier

Index: Dennis,W.E.; Speier,J.L. Journal of Organic Chemistry, 1970 , vol. 35, p. 3879 - 3884

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Citation Number: 8

Abstract

The addition of aminosilicon hydrides and silazane hydrides to olefins and to dimethylaminodimethylvinylsilane in the presence of chloroplatinic acid was studied. n- Butylaminodimethylsilane and hexene-1 formed 2-n-butyl-ln-hexyl-l, 1, 3, 3- tetramethyldisilazane which diminished a. 3 the reaction proceeded to form n- butylaminohexyldimethylsilane. Dialkylaminodimethylsilanes and trisdiniethylaminosilane ...