European Journal of Organic Chemistry

Enantioselective Synthesis of Benzyl tert??Butyl Sulfoxides

MK Syed, M Casey

Index: Syed, Majid Khalil; Casey, Mike European Journal of Organic Chemistry, 2011 , # 35 p. 7207 - 7214

Full Text: HTML

Citation Number: 4

Abstract

Abstract Enantiomerically pure benzyl sulfoxides are effective tools for the formation of new C–C bonds with control of configuration at new stereogenic centres. The reaction of enantioenriched tert-butyl tert-butanethiosulfinate with benzyllithium derivatives, obtained by deprotonation of the corresponding toluene derivatives, gave a wide variety of benzyl tert- butyl sulfoxides with complete inversion of configuration. The benzyl sulfoxides were ...

Related Articles:

A convenient procedure for the oxidation of sterically hindered sulfides to sulfoxides

[Drabowicz, Jozef; Lyzwa, Piotr; Popielarczyk, Miroslaw; Mikolajczyk, Marian Synthesis, 1990 , # 10 p. 937 - 938]

Asymmetric Synthesis of Aryl Benzyl Sulfoxides by Vanadium??Catalysed Oxidation: A Combination of Enantioselective Sulfide Oxidation and Kinetic Resolution in …

[Kelly, Padraig; Lawrence, Simon E.; Maguire, Anita R. European Journal of Organic Chemistry, 2006 , # 19 p. 4500 - 4509]

trans-(±)-2-tert-Butyl-3-phenyloxaziridine: A Unique Reagent for the Oxidation of Thiolates into Sulfenates

[Boudou, Cedric; Berges, Matthieu; Sagnes, Charlene; Sopkova-De Oliveira Santos, Jana; Perrio, Stephane; Metzner, Patrick Journal of Organic Chemistry, 2007 , vol. 72, # 14 p. 5403 - 5406]

Synthesis and X-ray crystal structure determination of 3, 4-diphenyl-6-(diphenylmethyl)-1, 5-dioxa-2-thiane-2-oxide

[Breau, L.; Sharma, N. K.; Butler, J. R.; Durst, T. Canadian Journal of Chemistry, 1991 , vol. 69, # 2 p. 185 - 188]

Reaction of singlet oxygen with some benzylic sulfides

[Bonesi, Sergio M.; Fagnoni, Maurizio; Monti, Sandra; Albini, Angelo Tetrahedron, 2006 , vol. 62, # 46 p. 10716 - 10723]

More Articles...