Tetrahedron letters

Photooxygenation of 1, 2-bis (silyloxy) cycloalkenes

W Adam, X Wang

Index: Adam, Waldemar; Wang, Xiaoheng Tetrahedron Letters, 1990 , vol. 31, # 9 p. 1245 - 1248

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Citation Number: 6

Abstract

Abstract The reaction of singlet oxygen with O-silylated cyclic enediols 1a, b afforded as ene products the hydroperoxy silyl enol ethers 3a, b and as cleavage products the silyl esters 4a, b; the latter presumably derived from rearrangement of the intermediary silylperoxy ketones 2a, b.

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