Intramolecular palladium-catalyzed trimethylenemethane cycloadditions: initial studies

BM Trost, TA Grese, DMT Chan

Index: Journal of the American Chemical Society, , vol. 113, # 19 p. 7350 - 7362

Full Text: HTML

Citation Number: 66

Abstract

... Ring construction constitutes a continuing major challenge in synthetic organic chemistry. ... 0 1991 American Chemical Society ... The common presence of bridgehead substituents, particularly methyl groups, in fused polycycles led us to synthesize the ac- ceptors 17 and 18. ...

Related Articles:

Synthesis of 2, 6-cis-disubstituted 4-methylenetetrahydropyrans by oxy-Michael addition

[Gill, Duncan; Taylor, Nicholas H.; Thomas, Eric J. Tetrahedron, 2011 , vol. 67, # 27-28 p. 5034 - 5045]

An intramolecular carbocyclic [3+ 2] cycloaddition via organopalladium intermediates

[Trost, Barry M.; Chan, Dominic M. T. Journal of the American Chemical Society, 1982 , vol. 104, # 13 p. 3733 - 3735]

Tris (trimethylsilyl) aluminum and transition-metal catalysts. Silylation of allyl acetates

[Trost, Barry M.; Yoshida, Jun-ichi; Lautens, Mark Journal of the American Chemical Society, 1983 , vol. 105, # 13 p. 4494 - 4496]

Regioselective synthesis of allyltrimethylsilanes from allylic halides and allylic sulfonates. Application to the synthesis of 2, 3-bis (trimethylsilyl) alk-1-enes

[Smith, Janice Gorzynski; Drozda, Susan E.; Petraglia, Susan P.; Quinn, Nina R.; Rice, Elizabeth M.; et al. Journal of Organic Chemistry, 1984 , vol. 49, # 22 p. 4112 - 4120]

More Articles...