Etude expérimentale et théorique de l'addition de l'acide hypochloreux sur les hydrocarbures alléniques

JP Bianchini, M Cocordano

Index: Bianchini,J.-P.; Cocordano,M. Tetrahedron, 1970 , vol. 26, p. 3401 - 3411

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Abstract

The addition of hypochlorous acid to allenic hydrocarbons leads, in all cases, to the fixation of the Cl atom on the central carbon and to the fixation of the OH group on the more substituted carbon. The (α-chloroketones which might be produced by the inverse fixation are not obtained. The utilisation of Hückel's method explains these results theoretically and satisfactorily.