Organometallics

Chemistry of heavy carbene analogs R2M (M= Si, Ge, Sn). 12. Concerted and nonconcerted insertion reactions of dimethylgermylene into the carbon-halogen bond

J Koecher, M Lehnig, WP Neumann

Index: Koecher, Juergen; Lehnig, Manfred; Neumann, Wilhelm P. Organometallics, 1988 , vol. 7, p. 1201 - 1207

Full Text: HTML

Citation Number: 29

Abstract

During the reaction of MezGe with CC13X (X= C1, Br), PhCHzX (X= Br, I), and PhzCHCl,'H CIDNP is observed in the products of net insertion of MezGe into the carbon-halogen bond and in MezGeXz (X= C1, Br). It is concluded that a two-step radical reaction takes place by ...

Related Articles:

Carbanions as intermediates in the formation of Grignard reagents

[Van Klink, Gerard P.M.; De Boer, Henricus J.R.; Schat, Gerrit; Akkerman, Otto S.; Bickelhaupt, Friedrich; Spek, Anthony L. Organometallics, 2002 , vol. 21, # 10 p. 2119 - 2135]

On the nature of the radical pairs involved in the Grignard reaction

[Boer, Henricus J. R. de; Akkerman, Otto S.; Bickelhaupt, Friedrich Angewandte Chemie, 1988 , vol. 100, p. 735 - 737]

Reactivity of N-(chlorodimethylgermyl) methyl and N-(chlorodimethylsilyl) methyl derivatives of lactams and amides toward Grignard reagents

[Bylikin; Shipov; Kramarova; Artamkina; Negrebetskii; Baukov Russian Journal of General Chemistry, 2004 , vol. 74, # 9 p. 1356 - 1358]

Photochemical reactions of vinyl-, styryl-, and benzyl-substituted digermanes

[Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 9 p. 2772 - 2777]

More Articles...