Phosphoramidate??Mediated Conversion of Carbonyl Ligands into Isocyanide Ligands: A New Approach to Chiral Isocyanide Ligands

…, C Pasquier, MA Peplow, JM Rushton…

Index: Gibson, Susan E.; Ibrahim, Hasim; Pasquier, Corinne; Peplow, Mark A.; Rushton, Julia M.; Steed, Jonathan W.; Sur, Ojit Chemistry - A European Journal, 2002 , vol. 8, # 1 p. 269 - 276

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Citation Number: 6

Abstract

Abstract Metal isocyanides have been used and studied by organometallic chemists for many years and, as a result, they have a rich and interesting chemistry. The nature of metal- free isocyanides and the methods of making isocyanide complexes, however, has resulted in the vast majority of studies to date being performed with structurally simple isocyanides. We report here a new approach to the synthesis of isocyanide ligands that involves the ...