The Journal of Organic Chemistry

Diethyl chlorophosphite: A mild reagent for efficient reduction of nitro compounds to amines

B Fischer, L Sheihet

Index: Fischer, Bilha; Sheihet, Larisa Journal of Organic Chemistry, 1998 , vol. 63, # 2 p. 393 - 395

Full Text: HTML

Citation Number: 31

Abstract

Phosphorus reagents are well established as deoxygenating agents in various important reactions such as Wittig, 1 Mitsunobu, 2 Arbuzov, 3 etc. The driving force in all these reactions is the high energy, ranging from 120 to 150 kcal/mol, released upon formation of phosphine oxide or phosphate products. 4 Cadogan and others reported the abstraction of oxygen from aromatic nitro and nitroso compounds by triethyl phosphites and related ...

Related Articles:

Copper-catalyzed aerobic oxidative cross-coupling of arylamines and dialkylphosphites leading to N-arylphosphoramidates

[Wang, Gao; Yu, Qing-Ying; Chen, Shan-Yong; Yu, Xiao-Qi Tetrahedron Letters, 2013 , vol. 54, # 46 p. 6230 - 6232]

Practical and reliable synthesis of dialkyl N-arylphosphoramidates with nitroarenes as substrates

[Haggam, Reda; Conrad, Juergen; Beifuss, Uwe Tetrahedron Letters, 2009 , vol. 50, # 48 p. 6627 - 6630]

More Articles...