Organic letters

One-Pot Palladium-Catalyzed Cross-Coupling Reaction of Aryl Iodides with Stannylarsanes and Stannylstibanes

M Bonaterra, SE Martín, RA Rossi

Index: Bonaterra, Mariana; Martin, Sandra E.; Rossi, Roberto A. Organic Letters, 2003 , vol. 5, # 15 p. 2731 - 2734

Full Text: HTML

Citation Number: 19

Abstract

The reaction of Ph3As and Ph3Sb with Na metal in liquid ammonia gives Ph2M-ions (M= As, Sb) that react with n-Bu3SnCl to afford n-Bu3Sn-MPh2 (1). The ammonia was allowed to evaporate, and toluene was added. The Pd-catalyzed cross-coupling reactions of these stannanes with aryl iodides afford functionalized triaryl-arsanes and triaryl-stibanes in high yields in a one-pot procedure (80-99%). The use of the commercially available, air-stable, ...

Related Articles:

Photostimulated reaction of diphenylarsenide and diphenylstibide ions with haloaromatic compounds by the SRN1 mechanism. Electron transfer vs. bond breaking of …

[Alonso, Ruben A.; Rossi, Roberto A. Journal of Organic Chemistry, 1982 , vol. 47, # 1 p. 77 - 80]

Photostimulated reaction of diphenylarsenide and diphenylstibide ions with haloaromatic compounds by the SRN1 mechanism. Electron transfer vs. bond breaking of …

[Alonso, Ruben A.; Rossi, Roberto A. Journal of Organic Chemistry, 1982 , vol. 47, # 1 p. 77 - 80]

Photostimulated reaction of diphenylarsenide and diphenylstibide ions with haloaromatic compounds by the SRN1 mechanism. Electron transfer vs. bond breaking of …

[Alonso, Ruben A.; Rossi, Roberto A. Journal of Organic Chemistry, 1982 , vol. 47, # 1 p. 77 - 80]

Tertiäre Arsine durch Umsetzung von Kaliumdiphenylarsid mit Salzen aromatischer Sulfonsäuren

[Schindlbauer,H.; Lass,H. Monatshefte fuer Chemie, 1968 , vol. 99, p. 2460 - 2467]

More Articles...