Monatshefte für Chemie/Chemical Monthly

Tertiäre Arsine durch Umsetzung von Kaliumdiphenylarsid mit Salzen aromatischer Sulfonsäuren

H Schindlbauer, H Lass

Index: Schindlbauer,H.; Lass,H. Monatshefte fuer Chemie, 1968 , vol. 99, p. 2460 - 2467

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Citation Number: 3

Abstract

Abstract The method developed for the preparation of tertiary and di-tertiary phosphines by reaction of potassium diphenylphosphide with alkali salts of aromatic sulfonic acids in high- boiling ethers as solvents was applied to the preparation of analogous arsenic compounds. It was possible to prepare in moderate yields some hitherto unknown aromatic arseno compounds. As a side reaction cleavage of the As− C bond yielding metallic arsenic ...

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