Intramolecular influence of a carboxylic function on platinum blue synthesis. A systematic study of complexes originating from acid amides

P Arrizabalaga, P Castan…

Index: Arrizabalaga, Philippe; Castan, Paule; Laurent, Jean-Pierre Journal of the American Chemical Society, 1984 , vol. 106, # 16 p. 4814 - 4818

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Citation Number: 17

Abstract

Abstract: The use of acid amide as ligand for obtaining platinum blue has been investigated. While blue compounds are generally obtained by using the hydrolysis product of cis- dichlorodiammineplatinum (I1) as platinum source, with such ligands the reaction occurs very readily using potassium tetrachloroplatinate (I1). The role of the carboxylic function which offers here a primary ligating site to platinum is evidenced. The compounds ...