Constitutional dynamic systems of ionic and molecular liquids

MD Soutullo, RA O'Brien, KE Gaines…

Index: Soutullo, Morgan D.; O'Brien, Richard A.; Gaines, Kyle E.; Davis, James H. Chemical Communications, 2009 , # 18 p. 2529 - 2531

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Citation Number: 8

Abstract

Demonstrating the viability of the concept of IL-based dynamic chemistry, 3 we describe here the reactions of protic nucleophiles with the new ILs N-methylpyridinium-2-carboxaldehyde bis(trifluoromethanesulfonyl)amide, 1, and N-methylpyridinium-3-carboxaldehyde bis(trifluoromethanesulfonyl)amide, 2. The cations of these materials readily and reversibly react in a holo (self-contained) 1d fashion with protic nucleophiles via their ...