Journal of organometallic chemistry

Diphenylphosphino (phenyl pyridin-2-yl methylene) amine palladium (II) complexes: Chemoselective alkene hydrocarboxylation initiators

PW Dyer, J Fawcett, MJ Hanton

Index: Dyer, Philip W.; Fawcett, John; Hanton, Martin J. Journal of Organometallic Chemistry, 2005 , vol. 690, # 23 p. 5264 - 5281

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Abstract

The heteroditopic, P–N-chelating ligand diphenylphosphino (phenyl pyridin-2-yl methylene) amine (1) has been synthesised via a simple 'one-pot'procedure and its donor characteristics assessed. The neutral [MX (Y)(1-κ2-P–N)](3, M= Rh, X= Cl, Y= CO; 4, M= Pd, X= Y= Cl; 5, M= Pd, X= Cl, Y= Me; 6, M= Pt, X= Y= Cl; 7, M= Pt, X= Cl, Y= Me; 8, M= Pt, X= Y= Me) and cationic [Pd (Me)(MeCN)(1-κ2-P–N)][Z](9, Z= B {3, 5-(CF3) 2-C6H3} 4; 10, Z= PF6 ...

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