The Synthesis of Solvent??Free Glycidic Esters from Diazoesters and Carbonyl Compounds Catalysed by Lanthanide Triflates
M Curini, F Epifano, MC Marcotullio…
Index: Curini, Massimo; Epifano, Francesco; Marcotullio, Maria Carla; Rosati, Ornelio Heterocycles, 2001 , vol. 55, # 8 p. 1599 - 1604
Full Text: HTML
Citation Number: 15
Abstract
Abstract The results of the reaction between ethyl diazoacetate and carbonyl compounds catalysed by lanthanide triflates are described. Aldehydes, and α-unsubstituted and α- monosubstituted cyclohexanones react to give the selective formation of α, β-epoxy esters