Carbohydrate research

Trichloroisocyanuric acid (TCCA): an efficient green reagent for activation of thioglycosides toward hydrolysis

N Basu, SK Maity, A Chaudhury, R Ghosh

Index: Basu, Nabamita; Maity, Sajal Kumar; Chaudhury, Aritra; Ghosh, Rina Carbohydrate Research, 2013 , vol. 369, p. 10 - 13

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Citation Number: 7

Abstract

Trichloroisocyanuric acid (TCCA), an inexpensive, commercially available, and non-toxic reagent has been used for the activation of thioglycosides toward their hydrolysis to the corresponding hemiacetals in high to excellent yields. The methodology provides a mild reaction condition for dealing with compounds containing acid sensitive functional groups.

Total synthesis of phenylpropanoid glycosides, grayanoside A and syringalide B, through a common intermediate

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NaBH 3 CN and other systems as substitutes of tin and silicon hydrides in the light or heat-initiated reduction of halosugars: a tunable access to either 2-deoxy sugars …

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Mild and efficient hydrolysis of thioglycosides to glycosyl hemiacetals using N-iodosaccharin

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