Journal of Organometallic Chemistry

Cyclopalladated ferrocenylimines: highly active catalysts for Heck reactions

Y Wu, J Hou, H Yun, X Cui, R Yuan

Index: Wu, Yangjie; Hou, Jianjun; Yun, Hongying; Cui, Xiuling; Yuan, Ruijuan Journal of Organometallic Chemistry, 2001 , vol. 637-639, p. 793 - 795

Full Text: HTML

Citation Number: 45

Abstract

A novel kind of ferrocene moiety containing palladacycle catalysts 1 and 2 was synthesized and applied to Heck arylation. High yields, turnover numbers and regioselectivity were achieved in moderate conditions. When 2.73× 10− 8 mol catalyst 2 was used to catalyze arylation of 0.1 mol iodobenzene with butyl acrylate, optimal results were obtained with 3.6× 106 turnover number and 99% yield.

Related Articles:

The palladium-catalysed arylation of activated alkenes with aroyl chlorides

[Blaser, Hans-Ulrich; Spencer, Alwyn Journal of Organometallic Chemistry, 1982 , vol. 233, # 2 p. 267 - 274]

Nucleophilic carbene-catalyzed redox-esterification reaction of α-halo-α, β-unsaturated aldehyde

[Wang, Xiang-Bo; Zou, Xiao-Lei; Du, Guang-Fen; Liu, Zhi-Yong; Dai, Bin Tetrahedron, 2012 , vol. 68, # 32 p. 6498 - 6503]

Arenediazonium o-benzenedisulfonimides as efficient reagents for Heck-type arylation reactions

[Artuso, Emma; Barbero, Margherita; Degani, Iacopo; Dughera, Stefano; Fochi, Rita Tetrahedron, 2006 , vol. 62, # 13 p. 3146 - 3157]

Practical Asymmetric Hydrogenation-Based Synthesis of a Class-Selective Histone Deacetylase Inhibitor

[Chintareddy, Venkat Reddy; Ellern, Arkady; Verkade, John G. Journal of Organic Chemistry, 2010 , vol. 75, # 21 p. 7166 - 7174]

A Simple Synthesis of (Nitroaryl) ethylene Derivatives via the Vicarious Nucleophilic Substitution of Hydrogen

[Makosza, M.; Tyrala, A. Synthesis, 1987 , # 12 p. 1142 - 1144]

More Articles...