Probing hyperconjugation experimentally with the conformational deuterium isotope effect

KT Greenway, AG Bischoff…

Index: Greenway, Kyle T.; Bischoff, Anthony G.; Pinto, B. Mario Journal of Organic Chemistry, 2012 , vol. 77, # 20 p. 9221 - 9226,6

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Citation Number: 10

Abstract

Hyperconjugation underlies many chemical phenomena of fundamental and practical importance. Owing to a great deal of interest in the anomeric effect, anomeric-like hyperconjugative effects have been thoroughly investigated in oxygen-containing systems. However, such interactions in the second-and third-row chalcogens are less well- understood and have generated some controversy. Here, we show that the conformational ...