Nitric oxide chemical ionization mass spectrometry of alcohols

DF Hunt, TM Harvey, WC Brumley, JF Ryan III…

Index: Hunt; Harvey; Brumley; Ryan III; Russell Analytical Chemistry, 1982 , vol. 54, # 3 p. 492 - 496

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Citation Number: 18

Abstract

RESULTS Data obtained from nitric oxide chemical ionization mass spectra of primary, 1-17, secondary, 18-26, and tertiary alcohols, 27-33, are presented in Table I. Product ions resulting from the reaction of NO+ with alcohols 34-41, labeled with deuterium on the a- carbon atom are summarized in Table 11. In general we find that the nitrosonium ion functions as an electrophile, hydride abstractor, and hydroxide ion abstractor toward ...