A General Rhodium??Catalyzed Cyanation of Aryl and Alkenyl Boronic Acids

P Anbarasan, H Neumann…

Index: Anbarasan, Pazhamalai; Neumann, Helfried; Beller, Matthias Angewandte Chemie - International Edition, 2011 , vol. 50, # 2 p. 519 - 522

Full Text: HTML

Citation Number: 99

Abstract

Transition-metal-catalyzed functionalization of organoboron derivatives has emerged as a powerful tool for the selective formation of carbon–carbon and carbon–heteroatom bonds in modern organic synthesis.[1] In addition to palladium-catalyzed coupling reactions, such as the famous Suzuki–Miyaura reaction, rhodium-catalyzed additions of aryl or alkenyl boronic acids to alkynes,[2] alkenes,[3] carbonyl compounds,[4] imines,[5] and nitriles [6, 7] are in ...

Related Articles:

Simple and efficient copper-catalyzed one-pot conversion of aldehydes into nitriles

[Capdevielle, Patrice; Lavigne, Andre; Maumy, Michel Synthesis, 1989 , # 6 p. 451 - 452]

Application of Polymer??Supported Triphenylphosphine and Microwave Irradiation to the Palladium??Catalyzed Cyanation of Aryl Triflates

[Srivastava, Rajiv R.; Zych, Andrew J.; Jenkins, David M.; Wang, Hong-Jun; Chen, Zhen-Jia; Fairfax, David J. Synthetic Communications, 2007 , vol. 37, # 3 p. 431 - 438]

Copper-Mediated Transformation of Organosilanes to Nitriles with DMF and Ammonium Iodide

[Wang, Zhen; Chang, Sukbok Organic Letters, 2013 , vol. 15, # 8 p. 1990 - 1993]

Cu2O??Mediated Room Temperature Cyanation of Aryl Boronic Acids/Esters and TMSCN

[Ye, Yong; Wang, Yanhua; Liu, Pengtang; Han, Fushe Chinese Journal of Chemistry, 2013 , vol. 31, # 1 p. 27 - 30]

Copper-Mediated Sequential Cyanation of Aryl C–B and Arene C–H Bonds Using Ammonium Iodide and DMF

[Kim, Jinho; Choi, Jiho; Shin, Kwangmin; Chang, Sukbok Journal of the American Chemical Society, 2012 , vol. 134, # 5 p. 2528 - 2531]

More Articles...