Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates
PV Ramachandran, D Pratihar, D Biswas…
Index: Ramachandran, P. Veeraraghavan; Pratihar, Debarshi; Biswas, Debanjan; Srivastava, Amit; Reddy, M. Venkat Ram Organic Letters, 2004 , vol. 6, # 4 p. 481 - 484
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Citation Number: 77
Abstract
A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis- Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish β- substituted-α-methylene-γ-butyrolactones stereoselectively.
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