New π-Extended Donors: Synthesis, Characterization, Electrochemical and Electrical Conductivity Studies

…, A Gouasmia, S Bouguessa, L Kaboub…

Index: Zitouni, Amel; Gouasmia, Abdelkrim; Bouguessa, Sabrina; Kaboub, Lakhemici; Boudiba, Louiza Phosphorus, Sulfur and Silicon and the Related Elements, 2011 , vol. 186, # 8 p. 1744 - 1754

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Abstract

A new series of tetrathiafulvalene (TTF) molecules with extended π-system was prepared by using a Wittig reaction to generate the TTF key. The process of deprotection-alkylation of thiolates provided access to a wide variety of molecules. The study of their reducing power was carried out by cyclic voltammetry. Charge transfer complexes have also been chemically prepared by using TCNQ as an electron acceptor; the electrical conductivity of ...

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