Tetrahedron Letters

A synthesis and some reactions of 2-thiocyanato-2-ethylenic carbonyl compounds

Y Tamura, T Kawasaki, N Gohda, Y Kita

Index: Tamura,Y. et al. Tetrahedron Letters, 1979 , # 13 p. 1129 - 1132

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Citation Number: 6

Abstract

Abstract A synthesis of 2-thiocyanato-2-ethylenic carbonyl compounds was achieved by the reaction of epoxy ketones with Ph 3 P (SCN) 2 (TPPT). Some useful transformations of 2- thiocyanato-2-cyclohexenone to 2, 3-disubstituted cyclohexanones and iminothiazolines are described.