Journal of the Indian Chemical Society

Solvent hydrogen bonding and structural effects on nucleophilic substitution reactions. Part-7: Reaction of benzenesulphonyl chloride with substituted benzylamines in …

A Thirumoorthi, KP Elango

Index: Thirumoorthi; Elango Journal of the Indian Chemical Society, 2010 , vol. 87, # 7 p. 797 - 802

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Abstract

Résumé/Abstract Substitution reactions of eleven para-and meta-substituted benzylamines with benzenesulphonyl chloride in different mole fractions of dimethylsulfoxide (DMSO) in acetonitrile (AcN) have been investigated conductometrically. The second order rate constants found to increase with an increase in the mole fraction of DMSO up to 0.5 mole fraction and beyond that it remained nearly constant. Multiple correlation analysis of the ...

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