Chemical Communications

Catalysed aerobic dehydrogenation of amines and an X-ray crystal structure of a bis (benzylamine) ruthenium (II) porphyrin species

AJ Bailey, BR James

Index: Bailey, Alan J.; James, Brian R. Chemical Communications, 1996 , # 20 p. 2343 - 2344

Full Text: HTML

Citation Number: 49

Abstract

The complex trans-[RuVI (tmp)(O) 2] 1 (tmp= dianion of 5, 10, 15, 20-tetramesitylporphyrin) catalytically dehydrogenates primary and secondary amines in the presence of air; possible reaction steps involve a disproportionation reaction that generates a RuII intermediate, as evidenced by the isolated bis (benzylamine) complex [RuII (tmp)(PhCH2NH2) 2] 2 which is characterised crystallographically.

Related Articles:

An alternative pathway for production of acetonitrile: ruthenium catalysed aerobic dehydrogenation of ethylamine

[Corker, Emily C.; Mentzel, Uffe V.; Mielby, Jerrik; Riisager, Anders; Fehrmann, Rasmus Green Chemistry, 2013 , vol. 15, # 4 p. 928 - 933]

Synthesis of stenusine, the spreading agent of the beetle Stenus comma

[Stevens, Christian; Kimpe, Norbert de Journal of Organic Chemistry, 1993 , vol. 58, # 1 p. 132 - 134]

Acetylenes as potential antarafacial components in concerted reactions. Formation of pyrroles from thermolyses of propargyl amines, of a dihydrofuran from a …

[Viola, Alfred; Collins, John J.; Filipp, Nicholas; Locke, John S. Journal of Organic Chemistry, 1993 , vol. 58, # 19 p. 5067 - 5075]

Über N??Isocyan??dialkylamine

[Bredereck,H. et al. Justus Liebigs Annalen der Chemie, 1965 , vol. 686, p. 92 - 101]

Gas phase thermolysis of allyl cyanomethyl amine, diallyl cyanomethyl amine, diethyl cyanomethyl amine, and diethyl propargyl amine

[Martin, Gonzalo; Ascanio, Julian; Rodriguez, Jesus International Journal of Chemical Kinetics, 1995 , vol. 27, # 2 p. 99 - 108]

More Articles...