Tetrahedron

Fast and efficient preparation of Baylis–Hillman-derived (E)-allylic azides and related compounds in aqueous medium

MM Sá, MD Ramos, L Fernandes

Index: Sa, Marcus M.; Ramos, Marcia D.; Fernandes, Luciano Tetrahedron, 2006 , vol. 62, # 50 p. 11652 - 11656

Full Text: HTML

Citation Number: 60

Abstract

A practical access to alkyl-and aryl-substituted (E)-2-(azidomethyl) alkenoates and related azido compounds from the corresponding allylic bromides in aqueous acetone is described. An alternative method to obtain the starting bromides based on heterogeneous catalysis under mild conditions was also investigated.

Related Articles:

An Efficient Catalytic Asymmetric Synthesis of a β2-Amino Acid on Multikilogram Scale

[Luehr, Susan; Holz, Jens; Zayas, Odalys; Wendisch, Volkmar; Boerner, Armin Tetrahedron Asymmetry, 2012 , vol. 23, # 17 p. 1301 - 1319]

An Efficient Catalytic Asymmetric Synthesis of a β2-Amino Acid on Multikilogram Scale

[Luehr, Susan; Holz, Jens; Zayas, Odalys; Wendisch, Volkmar; Boerner, Armin Tetrahedron Asymmetry, 2012 , vol. 23, # 17 p. 1301 - 1319]

More Articles...