Oxidative Addition of 2-Haloalkene to Zirconocene

…, R Fischer, Y Nishihara, K Nakajima

Index: Takahashi, Tamotsu; Kotora, Martin; Fischer, Reinald; Nishihara, Yasushi; Nakajima, Kiyohiko Journal of the American Chemical Society, 1995 , vol. 117, # 44 p. 11039 - 11040

Full Text: HTML

Citation Number: 72

Abstract

Alkenylzirconocene compounds, which are easily prepared by the hydrozirconation of alkynes, have been very useful intermediates in organic synthe~ is.~-~ Hydrozirconation of terminal alkynes regio-and stereoselectively affords alkenylzirconocene compounds of type Even though compound I1 is formed in situ, it immediately isomerizes to I in the presence of C~~ ZIHC~.~.~~ Consequently, an alkenylzirconocene of type II cannot be obtained by ...

Related Articles:

Regioselective allylgallation of terminal alkynes

[Lee, Phil Ho; Heo, Yunkiu; Seomoon, Dong; Kim, Sundae; Lee, Kooyeon Chemical Communications, 2005 , # 14 p. 1874 - 1876]

Preparation of 1, 4-dienes from 2-(2-hydroxyalkylseleno) benzothiazoles by the reaction involving Se. RAR. O aza-aromatic ring rearrangement.

[Shibata, Koichi; Shiono, Hirofumi; Mitsunobu, Oyo Chemistry Letters, 1991 , # 4 p. 661 - 664]

Allyl-and Benzylindium Reagents. Carboindation of Carbon-Carbon and Carbon-Nitrogen Triple Bonds

[Fujiwara, Naoya; Yamamoto, Yoshinori Journal of Organic Chemistry, 1999 , vol. 64, # 11 p. 4095 - 4101]

More Articles...