Journal of organometallic chemistry

Zur Synthese neuartiger Triflate der 14. Gruppe

W Uhlig

Index: Uhlig, W. Journal of Organometallic Chemistry, 1991 , vol. 409, # 3 p. 377 - 383

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Abstract

Abstract Trifluoromethanesulfonates of silicon, germanium, tin and lead are obtained by cleavage of the corresponding phenyl derivatives with CF 3 SO 3 H. Selective cleavage of the tin carbon bond is observed in the case of silyl-and germylstannanes. Reaction of bis ( trifluoromethanesulfonates) with lithiumorganic compounds leads to functional substituted triflate derivatives.

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