Tetrahedron letters

A formal insertion of dichlorocarbene into a C Ar S bond

P Müller, G Bernardinelli, N Pautex

Index: Mueller, Paul; Bernardinelli, Gerald; Pautex, Nicole Tetrahedron Letters, 1988 , vol. 29, # 46 p. 5877 - 5880

Full Text: HTML

Citation Number: 4

Abstract

Abstract Reaction of phase transfer generated dichlorocarbene with 9- thiomethylphenanthrene (4) leads to 6 rather than the expected addition product 5. 6 is formally derived from a carbene insertion into the C, S bond. 13 C-labelling shows that the CH 3 group of 4 is lost during the reaction.

Related Articles:

Reductive photocarboxylation of phenanthrene: A mechanistic investigation

[Nikolaitchik, Alexander V.; Rodgers, Michael A. J.; Neckers, Douglas C. Journal of Organic Chemistry, 1996 , vol. 61, # 3 p. 1065 - 1072]

Singlet-Singlet, Triplet-Triplet, and “Optically-Controlled” Energy Transfer in Polychromophores. Preliminary Models for a Molecular Scale Shift Register

[McGimpsey; Samaniego; Chen; Wang Journal of Physical Chemistry A, 1998 , vol. 102, # 45 p. 8679 - 8689]

The Five Monocarboxylic Acids of Phenanthrene1, 2

[Journal of Organic Chemistry, , vol. 25, p. 499 - 503]

The Five Monocarboxylic Acids of Phenanthrene1, 2

[Journal of Organic Chemistry, , vol. 25, p. 499 - 503]

The Five Monocarboxylic Acids of Phenanthrene1, 2

[Journal of Organic Chemistry, , vol. 25, p. 499 - 503]

More Articles...