Photodetachment of the azide anion in the gas phase. Electron affinity of the azide radical

…, MJ Pellerite, JI Brauman

Index: Jackson, Robert L.; Pellerite, Mark J.; Brauman, John I. Journal of the American Chemical Society, 1981 , vol. 103, # 7 p. 1802 - 1805

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Citation Number: 33

Abstract

Conclusions The experimental results indicate that there is no rotation around the double bonds in the ionization of 2, bhexadiene isomers. Each ion structure has a unique photodissociation spectrum, and spectral differences are in accord with the molecular orbital calculations. The spectral differences of the 2, 4 isomers are greater in the visible region than those seen for the 1-chloropropene isomers, I0 and there are also differences, ...

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