Tetrahedron letters

6-bromo-6-(trimethylstannyl) bicyclo [3.1. 0] hexane as a thermal precursor of 1, 2-cyclohexadiene

A Runge, W Sander

Index: Runge, Andreas; Sander, Wolfram Tetrahedron Letters, 1986 , vol. 27, # 48 p. 5835 - 5838

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Citation Number: 16

Abstract

Abstract Flash vacuum pyrolysis and matrix-isolation studies of 6-bromo-6-(trimethylstannyl) bicyclo [3.1. 0] hexane (1) gave evidence for the formation of 1, 2-c. yclohexadiene (2) from this precursor. At high temperatures (600 C) 2 is not stable and fragmentates to 1-butene-3- yne (4) and ethylene.