Journal of the American Chemical Society

Cyclic Polyolefins. XXIV. 1, 2-Diphenylcycloöctatetraene1

AC Cope, DS Smith

Index: Cope; Smith Journal of the American Chemical Society, 1952 , vol. 74, p. 5136,5139

Full Text: HTML

Citation Number: 16

Abstract

1, 2-Diphenylcyclooctatetraene (I) has been prepared by copolymerization of diphenylacetylene with acetylene; o-diphenylbenzene was formed as a by-product. Evidence for the structure of 1, 2-diphenylcyclooctatetraene was obtained by hydrogenation, in which a large amount of cis-and a small amount of trans-1, 2-diphenylcyclooctane were formed. The structure of cis-1, 2-diphenylcyclooctane was confirmed by an independent ...

Related Articles:

Carbonyl regeneration from p-toluenesulfonylhydrazones (tosylhydrazones)

[Sacks,C.E.; Fuchs,P.L. Synthesis, 1976 , p. 456 - 457]

Photostimulated arylation of ketone enolate ions by the SRN1 mechanism

[Bunnett,J.F.; Sundberg,J.E. Journal of Organic Chemistry, 1976 , vol. 41, p. 1702 - 1706]

Direct α-arylation of ketones: The reaction of cyclic ketone enolates with diphenyliodonium triflate

[Ryan, John H.; Stang, Peter J. Tetrahedron Letters, 1997 , vol. 38, # 28 p. 5061 - 5064]

More Articles...