Synthesis and reactions of [tris (trimethylsilyl) methyl] ethyl dichlorosilane

KD Safa, MH Nasirtabrizi, UM Oskoei

Index: Safa, Kazem D.; Pour, A. Hassan; Nasirtabrizi, Mohammad H.; Oskoei, U. Mosaei Journal of Organometallic Chemistry, 2005 , vol. 690, # 6 p. 1606 - 1611

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Citation Number: 14

Abstract

The crowded dichlorosilane TsiSiEtCl2,(1),(Tsi=(Me3Si) 3C) was prepared from the reaction between EtSiCl3 and TsiLi, then it was reduced with LiAlH4 to give TsiSiEtH2,(2). The hydride (2) was then treated with two equivalents of ICl/CCl4 or Br2/CCl4 to produce TsiSiEtI2,(3), and TsiSiEtBr2,(4), respectively. The reaction of compound (2) with one equivalent of ICl/CCl4 gives TsiSiEtHI,(5). This product reacted with H2O/dioxane in the ...