Oxidation of Phosphites by Means of p-Quinones and Benzyl Alcohol

O Mitsunobu, K Kodera, T Mukaiyama

Index: Mitsunobu,O. et al. Bulletin of the Chemical Society of Japan, 1968 , vol. 41, p. 461 - 464

Full Text: HTML

Citation Number: 0

Abstract

Triethyl phosphite and tri-n-butyl phosphite were oxidized to the corresponding trialkyl phosphates by means of p-quinones and benzyl alcohol. On the other hand, when diethyl (N- diethyl) phosphoroamidite was treated with p-benzoquinone and benzyl alcohol, 4- ethoxyphenyl ethyl (N-diethyl) phosphoroamidate was obtained in a 69% yield and no diethyl (N-diethyl)-phosphoroamidate was isolated. The reaction of 2, 3, 5, 6- ...

Chloranil-sensitized photolysis of benzyltrimethylsilanes. Solvent effect on the competition between carbon-hydrogen and carbon-silicon bond cleavage

[Baciocchi, Enrico; Giacco, Tiziana Del; Elisei, Fausto; Ioele, Marcella Journal of Organic Chemistry, 1995 , vol. 60, # 24 p. 7974 - 7983]

Reactions of aryldiazomethanes with chloranil.

[Oshima, Takumi; Nagai, Toshikazu Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 3 p. 726 - 730]

The Reaction of Chloranil with the Decomposition Products from Azonitriles

[Hammond; Lucas Journal of the American Chemical Society, 1955 , vol. 77, p. 3249]