Etude quantitative des réactions d'ozonolyse. XIII. Sur la structure du zwitterion de Criegee

G Klutsch, J Grignon, J Renard…

Index: Klutsch,G. et al. Canadian Journal of Chemistry, 1970 , vol. 48, p. 1598 - 1606

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Citation Number: 7

Abstract

The hydroxyperoxides R2CH (OOR1) OH (R1= CH3, C2H5; R2= CH3, i-C3H7) and their isomeric alkoxyhydroperoxides R2CH (OOH) OR1 can be differentiated by their polarographic behavior. These hydroxyperoxides are not produced in the ozonolysis of trans 4-methyl-2-pentene in the presence of methanol or ethanol. It is concluded that the zwitterionic structure does not participate in the mechanism of ozonide formation.

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