The stereochemistry of addition of cyclopropanes to tetrachloro (diethylene) platinum (II)

N Dominelli, AC Oehlschlager

Index: Dominelli,N.; Oelschlager,A.C. Canadian Journal of Chemistry, 1977 , vol. 55, p. 364 - 370

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Citation Number: 13

Abstract

The synthesis of trans-1-n-hexyl-cis-2, 3-dideuterio cyclopropane and cis-1-n-hexyl-cis-2, 3- dideuterio cyclopropane are reported. These specifically deuterated cyclopropanes were reacted with tetrachloro (diethylene) diplatinum to yield the product (dichloro (2-n- hexylpropane-1, 3-diyl) platinum) of addition of Pt11 across the cyclopropyl C2C3 bond. It was shown by nmr spectroscopic analysis of the deuterated cyclopropanes and the ...