Reversibility in the Formation of Oxo (peroxo) porphyrinatomolybdenums.

…, K Hoshiba, Y Sasaki, T Imamura

Index: Fujihara, Tetsuaki; Hoshiba, Koji; Sasaki, Yoichi; Imamura, Taira Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 2 p. 383 - 389

Full Text: HTML

Citation Number: 13

Abstract

Reversibility in the formation reaction of a series of the oxo (peroxo) porphyrinatomolybdenums,[Mo VI O (tmp)(O 2)] 1,[Mo VI O (tdcpp)(O 2)] 2,[Mo VI O (ttp)(O 2)] 3,[Mo VI O (tdmpp)(O 2)] 4, and [Mo VI O (tpp)(O 2)] 5, was studied. In these dioxygen complexes with various porphyrin rings, two complexes, 2 and 4, were newly prepared by the solid-state reactions of corresponding Mo (IV) complexes with O 2. All the complexes ...

Related Articles:

Quantum chemical description of oxygen activation process on Co, Mn, and Mo porphyrins

[Ledon, Henry J.; Durbut, Patrick; Vareson, Francois Journal of the American Chemical Society, 1981 , vol. 103, # 12 p. 3601 - 3603]

Mechanism of the reactions of oxomolybdenum (V) tetraphenylporphyrin complex with alcohols in the presence of superoxide

[Imamura; Hasegawa; Tanaka; Nakajima; Fujimoto Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 1 p. 194 - 197]

Electrochemistry of para-substituted oxomolybdenum (V) tetraphenylporphyrin complexes

[Topich, Joseph; Berger, Norman Inorganica Chimica Acta, 1982 , vol. 65, p. L131 - L134]

More Articles...