Study of Phase Transfer Catalysis by Layered Scintillation Method

T Hideshima, M Morinaga, H Kimizuka

Index: Hideshima; Morinaga; Kimizuka Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 1 p. 85 - 89

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Citation Number: 2

Abstract

The static and kinetic feature of the reaction of sodium cyanide with 1-bromoalkanes in the presence of various phase transfer catalysts was investigated in the oil/water system by using a layered scintillation method and the mechanism of catalytic action was discussed. From the measurement of equilibrium constants for both reactions of hexadecyltrimethylammonium cyanide with 1-bromooctane and of sodium cyanide with ...