Inorganica chimica acta

An exact coordination mode of 6-thiopurine with an organotin (IV): preparation and crystal structure of triphenyl (6-thiopurinyl) tin (IV)

R Zhang, F Li, C Ma

Index: Zhang, Rufen; Li, Feng; Ma, Chunlin Inorganica Chimica Acta, 2004 , vol. 357, # 9 p. 2759 - 2762

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Abstract

Triphenyl (6-thiopurinyl) tin has been prepared and its structure reinvestigated by X-ray diffraction. In the structure, a new coordination mode was observed that was different from those reported previously from investigations by infrared and Mössbauer spectroscopy. In the molecule, 6-thiopurine coordinated to tin by the S and N (1) atoms. The discrete molecules were connected to form a zigzag 1D network through intermolecular H⋯ N ...