The Journal of Organic Chemistry

Slow nitrogen inversion due to intramolecular hydrogen bonding. Slow nitrogen inversion in diethyl 2-aziridinylphosphonate from the paramagnetic-induced shifts in …

S Rengaraju, KD Berlin

Index: Rengaraju,S.; Berlin,K.D. Journal of Organic Chemistry, 1972 , vol. 37, # 21 p. 3304 - 3310

Full Text: HTML

Citation Number: 24

Abstract

Retardation of pyramidal inversion of nitrogen was observed in diethyl 2- aziridinylphosphonate due to intramolecular hydrogen bonding. The presence of two invertomers has been shown by the nuclear magnetic resonance (nrnr) studies using the paramagnetic shift reagent tris (dipivalomethanato) europium (III)[Eu (DPhI) 3] ani benzene solvent shift studies.

Related Articles:

Synthesis, molecular structure, and spectroscopical properties of alkenylphosphonic derivatives. 1. Vinyl-, propenyl-,(bromoalkenyl)-, and (cyanoalkenyl) phosphonic …

[Sainz-Diaz, C. I.; Galvez-Ruano, E.; Hernandez-Laguna, A.; Bellanato, J. Journal of Organic Chemistry, 1995 , vol. 60, # 1 p. 74 - 83]

Etude de la réaction de cyclisation des halohydrines-1, 2 ethyl phosphonates de diéthyle pour l'obtention de l'époxy-1, 2 éthyl phosphonate de diéthyle

[Sturtz, G.; Pondaven-Raphalen, A. Phosphorus and Sulfur and the Related Elements, 1984 , vol. 20, p. 35 - 48]

More Articles...