Efficient Palladium??Catalyzed C O Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane

H Wang, L Li, XF Bai, JY Shang…

Index: Wang, Hu; Li, Li; Bai, Xing-Feng; Shang, Jun-Yan; Yang, Ke-Fang; Xu, Li-Wen Advanced Synthesis and Catalysis, 2013 , vol. 355, # 2-3 p. 341 - 347

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Citation Number: 15

Abstract

Abstract A simple method has been developed for the reductive deoxygenation of aromatic ketones and benzylic alcohols in the presence of polymethylhydrosiloxane (PMHS). The reductive deoxygenation of aromatic ketones and benzylic alcohols, including secondary alcohols, to the corresponding methylene hydrocarbons has been achieved in good to excellent yields using palladium chloride (PdCl 2) as catalyst and PMHS as hydride ...

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