Reactivity of Ether??and Amine??Complexed Dimers and Tetramers of Alkyllithiums towards Triphenylmethane

…, M Schakel, FJJ de Kanter, RF Schmitz…

Index: Moene, Willem; Vos, Marcel; Schakel, Marius; De Kanter, Frans J. J.; Schmitz, Robert F.; Klumpp, Gerhard W. Chemistry - A European Journal, 2000 , vol. 6, # 2 p. 225 - 236

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Citation Number: 6

Abstract

Abstract Kinetics of Lewis base (LB) complexed primary and secondary σ-alkyllithiums (RLi) with triphenylmethane (TPMH) are reported. Among the properties investigated are the effective reaction orders (see diagram), precomplexation and mechanism, and relative reactivities of tetrameric and dimeric RLis, both for primary and secondary R.

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