Lithium tetrakis-(N-dihydropyridyl)-aluminate: structure and reducing properties

PT Lansbury, JO Peterson

Index: Lansbury,P.T.; Peterson,J.O. Journal of the American Chemical Society, 1963 , vol. 85, p. 2236 - 2242

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Citation Number: 71

Abstract

Discussion Lithium tetrakis-(N-dihydropyridylj-aluminate (I), the responsible reducing agent generated from LAH and pyridine, is generated on a small scale by aging the orange- colored solution (ca. 0.25 M) for at least 24 hr. in a rubber-capped serum flask (initially at Oo, then at room temperature), from which aliquots can be removed by a hypodermic syringe. Crystalline I is obtained from more concentrated solutions (0.5 M) by filtration in a dry box ...