Negative polaron and triplet exciton diffusion in organometallic “Molecular Wires”
…, H Jiang, JR Miller, KS Schanze
Index: Liu, Yao; Jiang, Shujun; Glusac, Ksenija; Powell, David H.; Anderson, Danielle F.; Schanze, Kirk S. Journal of the American Chemical Society, 2002 , vol. 124, # 42 p. 12412 - 12413
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Citation Number: 50
Abstract
The dynamics of negative polaron and triplet exciton transport within a series of monodisperse platinum (Pt) acetylide oligomers is reported. The oligomers consist of Pt– acetylide repeats,[PtL2–C C–Ph–C C−] n (where L= PBu3 and Ph= 1, 4-phenylene, n= 2, 3, 6, and 10), capped with naphthalene diimide (NDI) end groups. The Pt–acetylide segments are electro-and photoactive, and they serve as conduits for transport of ...
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