The Reaction of sec-Alkyl Sulfides with p-Toluenesulfinic Acid1

JL Kice, EH Morkved

Index: Kice,J.L.; Morkved,E.H. Journal of Organic Chemistry, 1964 , vol. 29, p. 1942 - 1944

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Citation Number: 1

Abstract

The reaction of several see-alkyl sulfides with p-toluenesulfinic acid has been investigated. As with their primary counterparts, the principal reaction involves cleavage of the sulfide, the products being p-tolyl p-toluenethiolsulfonate, the sec-alkyl p-toluenethiolsulfonate, and the ketone derived from oxidation of the see-alkyl group. However, with 2-octyl sulfide the reaction appears to be somewhat more complex than usual, since some of the sulfide is ...