An enantioselective and highly convergent synthesis of (+)-ikarugamycin

RK Boeckman Jr, CH Weidner, RB Perni…

Index: Journal of the American Chemical Society, , vol. 111, # 20 p. 8036 - 8037

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Citation Number: 96

Abstract

... 1989, 111, 8036-8037 ... cleanly provided ester acetal 5 (90% from 4). Utilizing standard chemistry, 5 could be converted to aldehyde acetal 6, which as expected underwent epimerization to the more stable trans al- dehyde 3 on exposure to ... 0 1989 American Chemical Society ...